贺晓慧 教授/博导

发布时间:2016-09-02 12:49:00 点击:



贺晓慧,女,196612月出生,博士/博士后,南昌大学二级教授、博士生导师,材料科学与工程学院 高分子材料科学与工程系主任。2007入选江西省新世纪百千万人才工程,2013年被评为第十七批江西省主要学科学术和技术带头人,2007年和2009年被评为江西省中青年高分子材料学科带头人2004年毕业于中山大学高分子化学与物理专业,获理学博士学位,师从伍青教授;2008年在南昌大学材料物理与化学博士后流动站完成博士后研究工作出站,师从陈义旺教授;2009-2010年赴美国麻省理工学院(MIT)化学系做访问学者,师从2005年诺贝尔化学奖得主理查德·施罗克(Richard R. Schrock)教授。

目前在南昌大学材料科学与工程学院从事高分子材料科学与工程专业的教学和科研工作。主要研究兴趣和方向:烯烃聚合有机金属催化剂设计合成、结构与催化性能调控,烯烃催化配位可控聚合,高性能聚环烯烃设计合成,功能化聚环烯烃燃料电池离子交换膜材料,功能聚环烯烃锂离子电池聚合物电解质材料。  主持国家自然科学基金4项,江西省主要学科学术和技术带头人培养计划项目1项,江西省自然科学基金3项,江西省教育厅科技重点项目2项;研究成果在国际高水平的SCI源学术刊物上如Polym. Chem.J. Power SourceOrganometallicsMacromoleculeJ. Polym. Sci., Part A: Polym. Chem.Macromol. Chem. Phys. RSC Adv.等上发表研究论文70余篇。获授国家发明专利5项。共培养研究生40名,其中博士研究生6名。获得江西省自然科学奖二等奖1项,江西省科技进步奖一等奖1

至今共发表与环烯烃催化聚合、直接甲醇燃料电池离子交换膜材料应用研究、锂离子电池聚合物电解质应用研究相关的SCI论文40多篇,其中SCI影响因子3.0以上的达20多篇。

 

近年来主持的项目:

(1). 国家自然科学基金项目,21674045,基于功能环烯烃共聚的C-C桥联[N^O]配位单金属限制几何构型催化剂一步原位构筑、构-效关系及机理,2017/01-2018/12,在研,主持。 

(2). 国家自然科学基金项目,51463014,新型长效阻醇加成型聚降冰片烯基碱性阴离子交换膜的制备机理及其离子传输、阻醇、长期稳定性强化机制,2015/01-2018/12,在研,主持。

(3). 国家自然科学基金项目,21164006,空间立体几何构型α-酮亚胺配体后过渡金属催化剂合成及催化极性环烯烃共聚合,2011/01-2014/12,已结题,主持。

(4). 国家自然科学基金项目,50663002, 环烯烃衍生物配位催化聚合及其光学性能研究, 2007/1-2009/12, 已结题,主持。
(5). 江西省主要学科学术和技术带头人培养计划项目, 20133BCB22003, 高效共价键合纳米二氧化硅负载新型立体几何构型二亚胺镍(II)催化剂合成及其应用催化制备纳米复合聚降冰片烯材料,2013.1-2015.12.
(6). 江西省教育厅重点项目, GJJ12001,新型立体结构后过渡金属催化剂的分子结构设计、合成及催化应用, 2011.1-2013.12.
(7). 江西省自然科学基金项目, 2011GZH0091, 加成型磺化聚降冰片烯合成及其质子交换膜性能,2010.7-2013.7.
(8). 江西省教育厅科技项目,GJJ11275,新型基于加成型磺化聚降冰片烯质子传导膜的制备, 2011.1-2013.12.
(9). 江西省自然科学基金项目,2007GZH1704,有机稀土配合物催化环烯烃及其衍生物聚合研究,2007.7-2009.7.
(10). 国家中小企业技术创新基金项目,  06C26213600307, DQ-50环保型电气设备清洗剂,2006.7-2008.7.
代表性的论文:

1. Xiaohui He*, Xiong Jiang, Zijie Wang, Yingjiao Deng, Zhilong Han, Yingping Yang, Defu Chen, Cross-linked hydroxyl-conductive copolymer/silica composite membranes based on addition-type polynorbornene for alkaline anion exchange membrane fuel cell applications, Polymer Engineering & Science, 2018,58(1), 13-21.( IF:3.531)

2. Xaohui He*, ZijieWang, Weihua Zhou, Xiong Jiang, Zhilong Han, Defu Chen, Imidazolium-functionalized norbornene ionic liquid block copolymer and silica composite electrolyte membranes for lithium-ion batteries, Journal of Applied Polymer Science, 2017, 134(22),DOI: 10.1002/APP.44884.(IF:1.86)

3. Xiaohui He, * Zhilong Han,Yingping Yang, Suli Wang, Guangshui Tu, Feng Zhang, Shengmei Huang, Zijie Wang, Defu Chen, ROMP-type epoxy-functionalized norbornene copolymer and its hybrid alkaline anion exchange membranes preparation and application, RSC Advances, 2017, 7, 55977-55985.(IF:3.108)

4. Xiaohui He*, Yingjiao Deng, Xiong Jiang, Zijie Wang, Yingping Yang, Zhilong Han, Defu Chen, Copolymerization of norbornene and butyl methacrylate at elevated temperatures by a single centre nickel catalyst bearing bulky bis(α-diimine) ligand with strong electron-withdrawing groups, Polymer Chemistry, 2017, 8, 2390-2396. ( IF:5.375)

5. Xiaohui He,* Yingping Yang, Suli Wang, Zhilong Han, Guangshui Tu, Feng Zhang, Shengmei Huang, Zijie Wang, Defu Chen, Synthesis of bis-(benzocyclohexan-ketoimino) Ni(II) with different electron groups and their catalytic copolymerization of norbornene and polar norborneneRSC Advances, 2017, 7, 48745. ( IF:3.108)

6. Ping Huo, Jingbo Li, Wanyun Liu, Guangquan Mei, Xiaohui He, A highly active and thermally stable 6,13-dihydro-6,13-ethanopentacene-15,16-diimine nickel(II) complex as catalyst for norbornene polymerization, RSC Advances, 2017, 7, 51858–51863. ( IF:3.108)

7. Xiaohui He,* Yingjiao Deng,Zhilong Han,Yingping Yang, Defu Chen, Highly Symmetric Single Nickel Catalysts Bearing Bulky Bis(a-Diimine) Ligand: Synthesis, Characterization, and Electron-Effects on Copolymerization of Norbornene with 1-Alkene at Elevated Temperarure, Journal of Polymer Science Part A: Polymer Chemistry, 2016. 54,3495-3505. ( IF:2.952)

8. Jianwen Tian, Xiaohui He,* Jingyin Liu, Xiaodan Deng, Defu Chen, Palladium(ii) and copper(ii) chloride complexes bearing bulky α-diimine ligands as catalysts for norbornene vinyl-addition (co)polymerization, RSC Advances. 2016. 6, 22908-22916.( IF:3.108)

9. Jianwen Tian, Xiaohui He,* Jingyin Liu, Xiaodan DengDefu Chen, Synthhesis of well defined C-C bridged Ni(II) complexes bearing β-ketoiminato-fluorene ligands by bifluorenyl in situ coupling and application for norbornene (co)polymerization, RSC Advances. 2015. 5, 61851-61860. ( IF:3.108)

10. Xiaohui He,* Jingyin Liu, Hongyu Zhu, Yan ZhengDefu Chen, Novel quaternary ammonium functional addition-type norbornene copolymer as hydroxide-conductive and durable anion exchange membrane for direct methanol fuel cells, RSC Advances,  2015. 5, 63215-63225. (IF:3.108)

11. Juan Wang, Xiaohui He,* Hongyu Zhu, Defu Chen, Preparation of a ROMP-type imidazolium-functionalized norbornene ionic liquid block copolymer and the electrochemical property for lithium-ion batteries polyelectrolyte membranes, RSC Advances. 2015. 5, 43581-43588.(IF:3.108)

12. Ping Huo, Wanyun Liu, Xiaohui He,* Zhenhong Wei,Yiwang Chen*, Substituent effects and activation mechanism of norbornene polymerization catalyzed by three-dimensional geometry α-diimine palladium complexes, Polymer Chemistry, 2014, 5, 1210-1218. (IF:5.375)

13. Ping Huo, Wanyun Liu, Xiaohui He*, Yiwang Chen*, Norbornene/n-butyl methacrylate copolymerization over α-diimine nickel and palladium catalysts supported on multiwalled carbon nanotubes, Journal of Polymer Science Part A: Polymer Chemistry, 2014, 52, 3213–3220. (IF:2.952)

14. Lu Chen, Zhichuan Zhong, Chao Chen, Xiaohui He*, Yiwang Chen*, N,O-chelating bidentate Ni (II) and Pd (II) complexes for copolymerization of norbornene and norbornene ester, Journal of Organometallic Chemistry, 2014, 752, 100-108.( IF:2.184)

15. Xiaohui He*, Yan Zheng, Hongli Yao, Yiwang Chen*, Defu Chen, Hybrid Network Sulfonated Polynorbornene/Silica Membranes with Enhanced Proton Conductivity by Doped Phosphotungstic Acid, Fuel Cells, 2014, 1, 26-34.(IF:1.706)

16. Jianwen Tian, Hongyu Zhu, Jingyin Liu, Defu Chen, Xiaohui He*, Pd(II) complexes bearing di- and monochelate fluorinated β-ketonaphthyliminato ligand and their catalytic properties towards vinyl-addition polymerization and copolymerization of norbornene and ester-functionalized norbornene derivative, Applied Organometallic Chemistry, 2014, 28, 702-711.( IF:2.319)

17. Ping Huo, Wanyun Liu, Xiaohui He*, Hongming Wang, Yiwang Chen*, Ni(II) and Nickel (II) Complexes with Three-Dimensional Geometry α-Diimine Ligands: Synthesis and Catalytic Activity toward Copolymerization of Norbornene, Organometallics, 2013, 32, 2291-2299. (IF:3.862)

18. Xiaohui He*, Meiping Hu, Yi Wang Chen*, Defu Chen. Hybrid polyelectrolytes based on stable sulfonated polynorbornene with higher proton conductivity and lower methanol permeability. Journal of Power Sources, 2013, 242(35): 725-731.(IF:6.395)

19. Hongli Yao, Xiaohui He*, Lu Chen, Yiwang Chen*, Defu Chen, Vinyl-addition type norbornene copolymers containing flexible spacers and sulfonated pendant groups for proton exchange membranes, Journal of Applied Polymer Science, 2013, 128, 3540–3547. (IF:1.86)

20. Lie Chen, Xiaofeng Wang, Xiaohui He*, Shufang Liu, Yiwang Chen*, Weihua Zhou, Vinyl-addition Type Norbornene Copolymer Containing Sulfonated Biphenyl Pendant Groups for Proton Exchange Membranes, J. Appl. Polym. Sci. 2013, 127(3), 2280–2289. (IF:1.86)

21. Meiping Hu, Xiaohui He*, Yiwang Chen*, Defu Chen, Sulfonated Copoly(norbornene)s Bearing Sultone Pendant Groups and Application as Proton Exchange Membranes Candidates, Journal of Polymer Research. 2012, 19:9977. (IF:1.615)

22. Xiaofeng Wang, Jianqiang Hu, Ting Hu, Yanyun Zhang, Yiwang Chen*, Weihua Zhou, Shuqin Xiao, Xiaohui He, Crosslinked electrolytes based on poly(butoxymethylenenorbornene) for proton exchange membrane, Journal of Applied Polymer Science, 2012,123 (6), 3225–3233. (IF:1.86) 

23. Ran Huang, Xiaohui He*, Yiwang Chen, Huarong Nie, Weihua Zhou, Homo- and Copolymerization of Norbornene and 5-Norbornene-2-yl  Acetate with Bis-(β-ketonaphthylamino)Palladium(II)/B(C6F5)3 Catalytic System, Polymers for Advanced Technologies, 2012, 23(3), 483-490.(IF:1.907)

24. Xiaohui He, Kaiti Wang, Yiwang Chen, Bin Yuan, Surface-Initiated Addition Polymerization of Norbornene by a Pd(II) Catalyst Bearing Acetylacetone Ligand on the Glass Slide, Applied Surface Science, 2012, 258, 3779-3784.( IF:3.387)

25. Xiaohui He, Yueman Liu, Lu Chen, Yiwang Chen, Defu Chen, Ni(II) and Pd(II) Complexes Bearing Benzocyclohexan-ketoarylimine for Copolymerization of Norbornene with 5-Norbornene-2-Carboxylic Ester, Journal of Polymer Science Part A: Polymer Chemistry, 2012, 50 (22), 4695–4704.( IF:2.952)

26. Shufang Liu, Yiwang Chen*, Xiaohui He*, Lie Chen, Nie, Weihua Zhou, Stable Crosslinked Vinyl Addition Type Polynorbornene Graft Copolymer Proton Exchange Membranes, Journal of Applied Polymer Science, 2011, 121(2), 1166-1175.(IF:1.86)

27. Kaiti Wang,Yiwang Chen, Xiaohui He*, Yueman Liu, Weihua Zhou, Ni(II) and Pd(II) Complexes Bearing Novel Bis(b-ketoamino) Ligand  and Their Catalytic Activity toward Copolymerization of Norbornene and 5-Norbornene-2-yl Acetate Combined with B(C6F5)3, Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49(15), 3304-3313. (IF:2.952)

28. Yuepeng Xing, Yiwang Chen*, Xiaohui He*, Copolymerization of norbornene with methoxycarbonylnorbornene catalyzed by Ni{CF3C(O)CHC[N(naphthyl)]CH3}2/B(C6F5)3 catalytic system and good processability for Dry/Wet phase inversion and electrospinning techniqueJournal of Polymer Science Part A: Polymer Chemistry, 2011, 49(20), 4425-4432. (IF:2.952)

29. Bin Yuan, Xiaohui He*, Yiwang Chen, Kaiti Wang, Preparation of Nanosilica/Polynorbornene Nanocomposite by Covalently Immobilized Silica-Supported Acetylacetonate Palladium(II) Dichloride Catalyst, macromolecules chemistry and physics, 2011, 212, 2378-2388.(IF:3.531)

30. Yuepeng Xing, Xiaohui He*, Yiwang Chen, Huarong Nie, Qing Wu, Copolymerization of Norbornene and n-Butyl Methacrylate Catalyzed by Bis-(β-ketoamino)nickel(II)/B(C6F5)3 catalytic System, Polymer Bulletin, 2010, 65(1),13-23. (IF:1.43)

31. Xiaohui He*, Muqing Chen, Ling Shi, Fuping He, Weihua Zhou, Yiwang Chen*, Qing WuCopolymerization of Norbornene and 5-norbornene-2-yl acetate Using Novel Bis(β-ketoamino)Ni(II)/B(C6F5)3/AlEt3 Catalyst SystemJournal of Polymer Science Part A: Polymer Chemistry, 2009, 47(16) 3990-4000. (IF:2.95)

32. Xiaohui He, Yiwang Chen*, Yongming Liu, Shuxian Yu, Sanguo Hong, Qing Wu, Addition polymerization of norbornene using bis(β-ketoamino)nickel(II)/tris(pentafluorophenyl)borane catalytic systems, Journal of Polymer Science Part A: Polymer Chemistry, 2007, 45(20): 4733-4743.(IF:2.952)

33. Shuxian Yu, Xiaohui He*, Yiwang Chen*, Yongming Liu, Sanguo Hong, Qing Wu, Polymerization of styrene using bis(β-ketoamino)nickel(II)/methylaluminoxane catalytic systems, Journal of Applied Polymer Science, 2007, 105(2): 500-509.(IF:1.86)

22. Xiaohui He, Qing Wu, Polymerization of methyl methacrylate using bis(β-ketoamino)nickel(II)-MAO catalytic systems, Applied Organometallic Chemistry, 2006, 20 (4), 264-271.(IF:2.319)

34. Xiaohui He, Qing Wu, Polymerization of norbornene using bis(β-ketoamino)nickel(II)/MAO catalytic systems, Journal of Applied Polymer Science, 2006, 101( 6): 4172-4180.(IF:1.86)

35. Xiaohui He, Yingzheng Yao, Xiang Luo, Zhang Ling, Qing Wu, Ni(II) Complexes Bearing N,O-Chelate Ligands: Synthesis, Solid-Structure Characterization and Reactivity toward the Polymerization of Polar Monomer, Organometallics,2003, 22(24), 4952-4957. (IF:3.862)

专利:

1贺晓慧, 刘菁胤,田建文,邓小丹,一种C-C桥连[ONNO]-β-酮亚胺金属催化剂及制备方法,已授权。专利号:ZL 201510423212.52017.

2. 贺晓慧,陈义旺,王凯悌,姚溢琼。一种立体结构N,O-单配体金属催化剂及制备方法,专利号:ZL 201110299869.7, 2014

3. 贺晓慧,陈义旺,王凯悌,姚溢琼。一种立体结构N,O-双配体金属催化剂及制备方法,专利号:ZL 201110299867.8, 2014

 

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